BAUDRON Stéphane

Chargé de Recherches


Institut Le Bel

4 rue Blaise Pascal
CS 90032
67081 Strasbourg Cedex
France
Phone : + 33 (0)3 68 85 67 11
Fax : + 33 (0)3 68 85 14 21
E-mail : sbaudron@unistra.fr

Short biography

  • Born 1975
  • Undergraduate studies : École Nationale Supérieure de Chimie de Paris (1998)
  • Ph. D. : University of Angers (France) under the supervision of Dr. Patrick Batail (2002)
    Hydrogen bonding at the organic-inorganic interface as a tool for the construction of crystalline molecular materials
  • Post-Doc : University of California Berkeley under the supervision of Prof. Jeffrey R. Long (2002-2004)
    Lavoisier fellowship (French Ministry of Foreign Affairs)
  • Since 2004 : C.N.R.S. researcher (Chargé de recherches)
  • 2009 : Habilitation, Université de Strasbourg (France)
  • 2011 : JSPS short-term invitation fellowship. Laboratory of Prof. Susumu Kitagawa, Kyoto

Research interests

The design and elaboration of polymetallic species is of current interest owing to their applications in catalysis, magnetism and optics. However, a precise control of the relative arrangement of the different metal centres within such an assembly remains challenging. We are currently developing a strategy based on the sequential construction of heterobimetallic architectures in the crystalline state (see Figure). It relies on an organic ligand bearing two differentiated coordination poles which may be referred to as primary and secondary (respectively red and cyan in the figure below). This differentiation is tuned by the charge and/or the nature of the elements of the poles. As a result, a hierarchy in the coordination is induced.
Upon reaction with a first metal centre, M1, a discrete complex is formed. Such species may be isolated and characterized. It offers secondary coordination poles at its periphery. Therefore, upon assembly with another metal centre, M2, an heterometallic architecture can be formed. Depending on the number of available coordination sites as well as the coordination geometry of M2, both discrete polynuclear assemblies as well as infinite networks can be prepared.
This strategy is currently being applied using organic ligands such as 4,5-diazafluorene appended dithiolates and dipyrrins, among others.

Sequential construction strategy of heterometallic architectures

Graduate student

Damien Béchu (October 2016 - )

Undergraduate student

Former students

Graduate :

Dr. Domingo Salazar (Ph. D. November 2007) 

Currently an assistant professor, Universidad Technologica de la Mixteca (Mexico)

Dr. Dmitry Pogozhev (Ph. D. July 2010) 

Currently working for LG Chemicals, Moscow (Russia)

Dr. Catherine Bronner (Ph. D. October 2010) 

Currently a patent engineer (Paris)

Dr. Antoine Beziau (Ph. D. October 2014) 

Currently a project leader at BASF (Germany)

Dr. Fan Zhang (Ph. D. October 2017)

Undergraduate :

Victor Koehler (Mars-June 2017)

Antoine Mazel (March 2014 - June 2015)

Hervé Ruffin (June 2012 - June 2014)

Yanan Gu (October 2012 - June 2013) 

Liwen Feng (October 2012 - June 2013) 

Eric Moss (April - June 2010) 

Patrick Larpent (October 2009 - June 2010) 

Brandon Kilduff (REU summer student, June - August 2009) 

Publications

Book chapter

S. A.Baudron, in Ideas in Chemistry and Molecular sciences; Advances in Synthetic Chemistry, 2010, pp263-282, WileyVCH, Weinheim, B. Pignataro (ed.). (buy the book)

Differentiated ligands for the sequential construction of crystalline heterometallic architectures

Research and review articles

51) Ag(I)-pi interactions with pyrrolic derivatives

S. A. Baudron, Coord. Chem. Rev.,  2019, 380, 318-329.

50) Symmetrical and dissymmetrical 2,2'-bis-dipyrrin ligands and Zn(II) binuclear helicates

F. Zhang, S. A. Baudron, M. W. Hosseini, New J. Chem., 2018, 42, 6997-7004.

49) A Ni-2,2’-bisdipyrrinato complex as a potential sensitizer: synthesis and photoelectrochemical characterization

A. Poma, I. Grigioni, M. V. Dozzi, S. A. Baudron, L. Carlucci, M. W. Hosseini, E. Selli, New J. Chem., 2017, 41, 15021-15026.

48) Solvent and anion effects on the organization of a luminescent [2+2] BODIPY/Ag(I) metallamacrocycle in the crystalline state

F. Zhang, S. A. Baudron, M. W. Hosseini, CrystEngComm, 2017, 19, 4393-4400.

47) AzaBODIPY based coordination polymers

A. Mazel, S. A. Baudron, M. W. Hosseini, CrystEngComm 2017, 19, 897-900.

46) Preorganization of cleft for Ag-pi interaction in Zn(II) bisdipyrrin helicate for the construction of heterometallic networks

S. A. Baudron, M. W. Hosseini, Chem. Commun. 2016, 52, 13000-13003.

45) Luminescent Metal-Organic Frameworks based on dipyrromethene metal complexes and BODIPYS

S. A. Baudron, CrystEngComm 2016, 18, 4671-4680.

44) On Zn(II) 2?2'-bisdipyrrin circular helicates

S. A. Baudron, H. Ruffin, M. W. Hosseini, Chem. Commun. 2015, 51, 5906-5909.

43) Assembly, disassembly, and reassembly: conversion of homometallic coordination netwroks into mixed-metal organic frameworks

A. Béziau, S. A. Baudron, G. Rogez, M. W. Hosseini, Inorg. Chem. 2015, 54, 2032-2039.

42) Rigid yet flexible heteroleptic Co(III) dipyrrin complexes for the construction of heterometallic 1- and 2-D coordination polymers

A. Béziau, S. A. Baudron, D. Rasoloarison, M. W. Hosseini, CrystEngComm, 2014, 16, 4973-4980.

41) A silver bite: crystalline heterometallic architectures based on Ag-π interactions with a bis-dipyrrin zinc helicate

H. Ruffin, S. A. Baudron, D. Salazar-Mendoza, M. W. Hosseini, Chem. Eur. J., 2014, 20, 2449-2453.

40) From sequential to one-pot synthesis of dipyrrin based grid-type mixed metal-organic frameworks

A. Béziau, S. A. Baudron, A. Fluck, M. W. Hosseini, Inorg. Chem., 2013, 52, 14439-14448.

39) Ni(II) dipyrrin complexes bearing peripheral pyridyl or imidazolyl groups self-assemble into 2- and 3-D coordination polymers

A. Béziau, S. A. Baudron, G. Rogez, M. W. Hosseini, CrystEngComm, 2013, 15, 5980-5985.

38) Luminescent dipyrrin based metal complexes

S. A. Baudron, Dalton Trans., 2013, 42, 7498-7509.

37) Luminescent coordination polymers based on self-assembled cadmium dipyrrin complexes

A. Béziau, S. A. Baudron, A. Guenet, M. W. Hosseini, Chem. Eur. J., 2013, 19, 3215-3223.

36) From discrete tricyanovinylene appended 7-azaindole copper(II) paddlewheel to an infinite 1D network: synthesis, crystal structure and magnetic properties 

D. Pogozhev, S. A. Baudron, G. Rogez, M. W. Hosseini, Polyhedron, 2013, 52, 1329-1335.

35) Stepwise construction of grid-type Cu(II)/Cd(II) heterometallic MOFs based on an imidazole-appended dipyrrin ligand

A. Béziau, S. A. Baudron, D. Pogozhev, A. Fluck, M. W. Hosseini, Chem. Commun. 2012, 48, 10313-10315.

34) Heterometallic coordination polymers incorporating dipyrrin based heteroleptic copper and cobalt complexes: to Ag-π or not?

A. Béziau, S. A. Baudron, M. W. Hosseini, Dalton Trans. 2012, 41, 7227-7234. 

33) Excited state properties and energy transfer within dipyrrin-based binuclear iridium/platinum dyads: the effect of ortho-methylation on the spacer

C. Bronner, M. Veiga, A. Guenet, L. De Cola,  M. W. Hosseini, C. A. Strassert, S. A. Baudron, Chem. Eur. J., 2012, 18, 4041-4050. 

32) From insertion of rhodium acetate paddlewheels into functionalized 7-azaindole hydrogen bonded dimers to infinite architectures

D.Pogozhev, S. A. Baudron, M. W. Hosseini, Dalton Trans. 2011, 40, 7403-7411. 

31) Dithiolate appended iridium(III) complex with dual functions of reducing and capping agent for the design of small size gold nanoparticles 

G. Nasr, A. Guerlin, F. Dumur, S. A. Baudron, E. Dumas, F. Miomandre, G.Clavier, M. Sliwa, C. R. Mayer, J. Am. Chem. Soc. 2011, 133, 6501-6504. 

30) Dipyrrin based silver [2+2] metallamacrocycles

D.Pogozhev, S. A. Baudron, M. W. Hosseini, Dalton Trans. 2011, 40, 437-445. 

29) Heterometallic architectures based on the combination of heteroleptic copper and cobalt complexs with silver salts

B. Kilduff, D. Pogozhev, S. A. Baudron, M. W. Hosseini, Inorg. Chem. 2010, 49, 11231-11239. 

28) Carboxylic acid appended dipyrrin for the formation of a hexanuclear iridium/copper paddlewheel complex

C. Bronner, S. A. Baudron, M. W. Hosseini, Inorg.Chem. 2010, 49, 8659-8661. 

27) Dipyrrin based homo- and hetero-metallic infinite architectures

S. A. Baudron, CrystEngComm. 2010, 12, 2288-2295. Highlight in the New Talent themed issue. 

26) Combination of hydrogen and coordination bonding for the construction of one-dimensional networks based on a 7-azaindole appended dipyrrin 

D. Pogozhev, S. A. Baudron, M. W. Hosseini, CrystEngComm. 2010, 12, 2238-2244. 

25) Assembly of heteroleptic copper complexes with silver ions: from discrete trinuclear complexes to infinite networks

D. Pogozhev, S. A. Baudron, M. W. Hosseini, Inorg. Chem. 2010, 49, 331-338. 

24) Dipyrrin based luminescent cyclometallated palladium and platinum complexes

C. Bronner, S. A. Baudron, M. W. Hosseini, C. A. Strassert, A. Guenet, L. De Cola, Dalton Trans. 2010, 39, 180-184. 

23) Combination of primary amide and dipyrrin for the elaboration of extended architectures built upon both coordination and hydrogen bonding

S. A. Baudron, D.Salazar-Mendoza, M. W. Hosseini, CrystEngComm. 2009, 11, 1245-1254. 

22) Modular construction of a series of heteronuclear metallamacrocycles

S. A. Baudron, M. W. Hosseini, Chem. Commun. 2008, 4558-4560. 

21) Many faces of dipyrrins: from H-bonded networks to homo- and hetero-nuclear metallamacrocyles

D.Salazar-Mendoza, S. A. Baudron, M. W. Hosseini, Inorg. Chem. 2008, 47, 766-768. 

20) Beyond classical coordination: silver-p interactions in metal dipyrrin complexes

D. Salazar-Mendoza, S. A. Baudron, M. W. Hosseini, Chem. Commun. 2007, 2252-2254. 

19) A stepwise approach to the formation of heterometallic discrete complexes and infinite architectures

S. A. Baudron, M. W. Hosseini, N.Kyritsakas, M. Kurmoo, Dalton Trans. 2007, 1129-1139. 

18) Arranging up to six ferrocene carboxamide around metal centres 

D. Salazar-Mendoza, S. A. Baudron, M. W.Hosseini, N. Kyritsakas, A. DeCian, Dalton Trans. 2007, 565-569. 

17) Sequential generation of 1-D networks based on a differentiated bischelate-type ligand bearing both 4,5-diazafluorene and dithiolene units

S. A. Baudron, M. W. Hosseini, Inorg.Chem. 2006, 45, 5260-5262. 

16) Octanuclear cubic Cu(I) complex decorated with six peripheral chelates 

S. A. Baudron, M. W. Hosseini, N. Kyritsakas, New J. Chem. 2006, 30, 1083-1086. 

 

***************************Ph.D and post-doctoral work******************************

 

15) Crystalline patterns and band structure dimensionality in a series of conducting hybrids associating amide-functionalized EDT-TTF π-donors with the isosteric octahedral anions [FeNO(CN)5]2− and [M(CN)6]3− (M = Co, Fe)

L.V. Zorina, S.S. Khasanov, S.V. Simonov, R.P. Shibaeva, L.A. Kushch, L.I. Buravov, E.B. Yagubskii, S. Baudron, C. Mézière, P. Batail, E. Canadell, P. Auban-Senzier, Synth. Met. 2005, 155, 527-538. 

14) (EDT-TTF-CONH2)6[Re6Se8(CN)6], a metallic Kagomé-type organic-inorganic hybrid compound: electronic instability, molecular motion and charge localization

S. A. Baudron, P. Batail, C. Coulon, R. Clérac, E. Canadell, V. Laukhin, R. Melzi, P. Wzietek, D. Jérome, P. Auban-Senzier, S. Ravy, J. Am. Chem. Soc. 2005, 127, 11785-11797. 

13) Water nanodroplets confined in molecular nanobeakers

J. Fraxedas, A. Verdaguer, F. Sanz, S. Baudron, P. Batail, Surface Sci. 2005, 588, 41-48. 

12) A straightforward synthesis of diverse nickel dithiolene complexes appended with hydrogen bond donor/acceptor groups

S. A. Baudron, N. Avarvari, P. Batail, Inorg.Chem.2005, 44, 3380-3382. 

11) Functional p-donors with no symmetry and Mott physics 

P. Batail, K. Heuzé, S. A. Baudron, M. Fourmigué, C. Coulon, R. Clérac, E. Canadell, V. Laukhin, P. Auban-Senzier, R. Melzi, P. Wzietek, D. Jérome, J. Phys. IV France 2005, 131, 307-311. 

10) Transport properties of monocrystalline microwires of EDT-TTF(CONHMe)2 and (TMTSF)2ClO4

C. Colin, C. R. Pasquier, P. Auban-Senzier, F. Restagno, S. Baudron, P. Batail, J.Fraxedas, Synth. Met. 2004, 146, 273-277. 

9) Exploitation of the photochromic nitroprusside anion [FeNO(CN)5]2- as counterion for constructing molecular conductors: The first radical cation salts based on BDH-TTP and the amide functionalized derivatives of EDT-TTF 

R. Shibaeva, S. Khasanov, L. Zorina, S. Simonov, I. Shevyakova, L. Kushch, L. Buravov, E.Yagubskii, S. Baudron, C. Mézière, P. Batail, E. Canadell, J. Yamada, J. Phys. IV France, 2004, 114, 481-484. 

8) Structural isomerism in crystals of redox-active secondary ortho-diamides: the role of competing intra- and intermolecular hydrogen bonds in directing crystalline topologies 

S. A. Baudron, N. Avarvari, E.Canadell, P. Auban-Senzier, P. Batail, Chem. Eur. J. 2004, 10, 4498-4511.

7) Cluster-to-metal magnetic coupling: synthesis and characterization of 25-electron [Re6-nOsnSe8(CN)6](5-n)- (n = 1, 2) clusters and {Re6-nOsnSe8[CNCu(Me6tren)]6}9+ (n = 0, 1, 2) assemblies

E. G. Tulsky, N. R. M. Crawford, S. A. Baudron, P. Batail, J. R. Long, J. Am. Chem. Soc. 2003, 125,15543-15553.

6) Singular crystalline b’-layered topologies directed by ribbons of self-complementary amide···amide ring motifs in [EDT-TTF-(CONH2)2]2X (X = HSO4-, ClO4-, ReO4-, AsF6-): coupled activation of ribbon curvature, electron interactions and magnetic susceptibility

S. A. Baudron, N. Avarvari, P.Batail, C. Coulon, R. Clérac, E. Canadell, P. Auban-Senzier, J. Am.Chem. Soc. 2003, 125,11583-11590. 

5) Interdependence of redox state, hydrogen bonding, anion recognition and charge partition in crystals of (EDT-TTF-CONHMe)6[Re6Se8(CN)6](CH3CN)2(CH2Cl2)2

S. A. Baudron, P. Batail, C. Rovira, E. Canadell, R. Clérac, Chem. Commun. 2003, 1820-1821. 

4) Binuclear manganese compounds of potential biological significance. Part 1. Syntheses, structural, magnetic and electrochemical properties of dimanganese(II,II) and (II,III) complexes of a bridging phenolate ligand

L. Dubois, D.-F. Xiang, X.-S. Tan, J. Pécaut, P. Jones, S. Baudron, L. LePape, J.-M. Latour, C. Baffert, S. Chardon-Noblat, M.-N. Collomb, A. Deronzier, Inorg. Chem.2003, 42, 750-760

3) Bis(tetraphenylphosphonium) bis(cis-1,2-bis(methoxycarbonyl)ethylenedithiolato-k2S,S’)nickelate(II) and bis(tetraphenylphosphonium) bis(cis-1,2-bis(methoxycarbonyl)ethylenedithiolato-k2S,S’)nickelate(III) iodide : (PPh4)2[Ni(S2C2(CO2Me)2)2] and (PPh4)2[Ni(S2C2(CO2Me)2)2]I

S. A. Baudron, P. Batail,Acta Cryst.2002, C58, m575-m577. 

2) Interplay of charge transfer, dimensionality and amide hydrogen bond network adaptability in TCNQF4 complexes of EDO-TTF-CONH2 and EDT-TTF-CONH2

S. A. Baudron, C. Mézière, K. Heuzé, M. Fourmigué, P. Batail, P. Molinié, P. Auban-Senzier, J. Solid State Chem. 2002, 168, 668-674. 

1) Jahn-Teller distortion of the open-shell 23-electron chalcogenide rhenium cluster cores in crystals of the series, {[Re6Q8]3+(X-)6}3- (Q=S, Se; X=Cl, CN)

S. A. Baudron, A. Deluzet, K. Boubekeur, P. Batail, Chem. Commun. 2002, 2124-2125.